Photonic crystals are periodic dielectric or metallo-dielectric (nano)structures that are designed to affect the propagation of electromagnetic waves (EM) in the same way as the periodic potential in a semiconductor crystal affects the electron motion by defining allowed and forbidden electronic energy bands. The absence of allowed propagating EM modes inside the structures, in a range of wavelengths called a photonic band gap, gives rise to distinct optical phenomena such as inhibition of spontaneous emission, high-reflecting omnidirectional mirrors and low-loss-waveguiding among others.
Since the basic physical phenomenon is based on diffraction, the periodicity of the photonic crystal structure has to be in the same length-scale as half the wavelength of the EM waves i.e. ~300 nm for photonic crystals operating in the visible part of the spectrum. This makes the synthesis cumbersome and complex. To circumvent nanotechnological methods with their big and complex machinery, different approaches have been followed to grow photonic crystals as self-assembled structures from colloidal crystals.
A prominent example of a photonic crystal is the naturally occurring gemstone opal. Its play of colours is essentially a photonic crystal phenomenon based on Bragg diffraction of light on the crystal's lattice planes. Another well-known photonic crystal is found on the wings of some butterflies such as those of genus Morpho.
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